You can use the ExpMgrConfigReadByte function to read the byte value at a specific address in PCI configuration space.
OSErr ExpMgrConfigReadByte (
RegEntryIDPtr node,
LogicalAddress configAddr,
UInt8 *valuePtr);
The ExpMgrConfigReadByte function reads the byte at the address in PCI configuration space for device node node determined by offset configAddr, returning its value in valuePtr.